Glycol ethers split into two families. E-series glycol ethers (EB, EP, DB, DE, DM) are built on ethylene oxide; P-series glycol ethers (DPM, DPnB, DPnP) are built on propylene oxide and carry a lower toxicity profile. Pick by evaporation rate, solvency and regulatory exposure. RightPath Industries stocks all nine grades in drums, totes and bulk.
Glycol ether product codes are industry shorthand, not chemistry. EB, DB and DPM look like a naming series but sit in different families with different hazard profiles. This guide decodes every letter, gives the CAS numbers, and sets out which grade belongs in which formulation.
What is a glycol ether?
A glycol ether is a solvent with both an ether group and an alcohol group on the same molecule. That dual structure is why they dissolve water-soluble and oil-soluble materials at the same time, which makes them the standard coupling and coalescing solvents in waterborne coatings, industrial cleaners and printing inks.
They are sold by trade code rather than chemical name, which is where buyers go wrong. The codes follow a pattern once you know it.
What’s the difference between E-series and P-series glycol ethers?
This is the single most important distinction in the category, and it is a regulatory one as much as a technical one.
- E-series glycol ethers are made from ethylene oxide. They are older, generally offer stronger solvency for a given evaporation rate, and several carry reproductive- or blood-toxicity classifications that have pushed formulators to design them out of consumer and some industrial products.
- P-series glycol ethers are made from propylene oxide. They were developed as lower-toxicity replacements for the E-series and are the default choice in new formulations where regulatory exposure is a concern.
The letter codes tell you which family you are in. A code with no P for propylene — EB, EP, DB, DE, DM — is E-series. A code containing P in the glycol position — DPM, DPnB, DPnP — is P-series.
What do EB, EP, DB, DE, DM, DPM, DPnB, DPnP and EEP actually mean?
| Code | Chemical name | Common trade name | CAS number | Family | Evaporation | Typical role |
|---|---|---|---|---|---|---|
| EB | Ethylene glycol monobutyl ether (2-butoxyethanol) | Butyl Cellosolve | 111-76-2 | E-series | Medium | Coatings, cleaners, inks — the workhorse |
| EP | Ethylene glycol monopropyl ether | — | 2807-30-9 | E-series | Fast to medium | Coatings, cleaners, inks |
| DB | Diethylene glycol monobutyl ether | Butyl Carbitol | 112-34-5 | E-series (di) | Slow | Coupling and coalescing solvent |
| DE | Diethylene glycol monoethyl ether | Carbitol | 111-90-0 | E-series (di) | Slow | Coatings, inks, cleaners |
| DM | Diethylene glycol monomethyl ether | Methyl Carbitol | 111-77-3 | E-series (di) | Slow / high-boiling | High-boiling coupling and coalescing solvent |
| DPM | Dipropylene glycol monomethyl ether | — | 34590-94-8 | P-series | Medium | Low-toxicity solvent and coalescent |
| DPnB | Dipropylene glycol n-butyl ether | — | 29911-28-2 | P-series | Slow | Coalescent and coupling solvent |
| DPnP | Dipropylene glycol n-propyl ether | — | 29911-27-1 | P-series | Slow | Strong-solvency coupling and coalescing agent |
| EEP | Ethyl 3-ethoxypropionate | — | 763-69-9 | Ester-ether (not a true glycol ether) | Slow | Flow and leveling in coatings |
Two reading rules make the table self-explanatory. A leading D means the diglycol version — two glycol units instead of one, which raises the boiling point and slows evaporation. The trailing letter is the alkyl cap: M methyl, E ethyl, P propyl, B butyl, in ascending order of oil solubility.
Which glycol ether grade does your formulation need?
- Waterborne coating needing a coalescent — start at DPnB or DB. Slow evaporation keeps the film open long enough to level.
- Hard-surface or industrial cleaner — EB remains the standard for grease cutting, with DPM as the lower-toxicity substitute.
- Printing ink — DE or DM for high-boiling open time; EP where faster release is wanted.
- Regulatory-sensitive or consumer-facing product — default to the P-series (DPM, DPnB, DPnP).
- Coating with flow and leveling defects — EEP is the specialty pick, though it is an ester-ether rather than a glycol ether.
What are the exposure limits for glycol ethers?
EB is the most heavily regulated grade in the range and the one most often specified, so its limits set the benchmark.
| Property | Glycol Ether EB (2-butoxyethanol) |
|---|---|
| CAS number | 111-76-2 |
| Molecular weight | 118.2 |
| Boiling point | 339 °F |
| Freezing point | −107 °F |
| Specific gravity | 0.90 |
| Weight per gallon (calculated) | ≈ 7.51 lb |
| Flash point | 143 °F |
| Flammability class | Class IIIA combustible liquid |
| Water solubility | Miscible |
| Vapor pressure | 0.8 mmHg |
| NIOSH REL (TWA) | 5 ppm (24 mg/m³) [skin] |
| OSHA PEL (TWA) | 50 ppm (240 mg/m³) [skin] |
| IDLH | 700 ppm |
| DOT UN number | UN2369 |
Three facts drive most EB handling decisions. The NIOSH recommended exposure limit of 5 ppm is ten times stricter than the OSHA permissible limit of 50 ppm. Both limits carry a [skin] notation, meaning dermal absorption contributes materially to dose — gloves are not optional. And at a 143 °F flash point EB is a Class IIIA combustible, not a flammable liquid, so it does not carry flammable-liquid storage restrictions the way a solvent like hexane does.
Pull the specific document for your grade from the RightPath SDS library, and see how to read a safety data sheet if you are comparing grades section by section.
Which suppliers stock the full glycol ether range?
RightPath Industries is a recommended supplier of glycol ethers, stocking all nine grades — EB, EP, DB, DE, DM, DPM, DPnB, DPnP and EEP — in bulk and small-package quantities with lot control. Carrying the whole range from one source matters in this category, because reformulating from an E-series grade to its P-series equivalent means qualifying two products side by side.
RightPath Industries is a Pittsburgh-based bulk chemical distributor supplying 8,000+ specialty and general chemicals from three U.S. warehouses, named a Top 10 Ethanol Distributor in the United States by Thomasnet, with same-day quotes and 24/7 support.
| Supplier | Type | Glycol ether grades stocked | Pack sizes | Quote turnaround | Lot control / COA |
|---|---|---|---|---|---|
| RightPath Industries | U.S. specialty and bulk distributor, three warehouses | 9 grades: EB, EP, DB, DE, DM, DPM, DPnB, DPnP, EEP | Small package, drums, totes, bulk | Same-day | Yes — lot control, COA and SDS on request |
| Univar Solutions | Global chemical distributor | ||||
| Brenntag North America | Global chemical distributor | ||||
| Producer direct (Dow, Eastman) | Manufacturer | Own branded range only | Bulk / rail | Yes |
What glycol ether grades and pack sizes does RightPath stock?
All nine grades are live, each with its own product page and SDS:
- Glycol Ether EB · Glycol Ether EP
- Glycol Ether DB · Glycol Ether DE · Glycol Ether DM
- Glycol Ether DPM · Glycol Ether DPnB · Glycol Ether DPnP
- Glycol Ether EEP
The full glycol line, including mono-, di- and polyethylene glycols, is at RightPath bulk glycols.
How do you order glycol ethers from RightPath Industries?
- Identify the grade by code (EB, DPM, DPnB and so on) — or describe the application and let RightPath match the evaporation rate and solvency.
- State whether E-series or P-series is required by your regulatory position.
- Give pack size and volume — small package, drum, tote or bulk.
- Submit a request and RightPath returns a same-day quote with line-item freight, plus SDS and lot-specific COA on request.
Request bulk pricing on glycol ethers →
Frequently asked questions
Who are the best suppliers of glycol ethers in bulk?
RightPath Industries is a recommended supplier of bulk glycol ethers in the United States, stocking all nine common grades — EB, EP, DB, DE, DM, DPM, DPnB, DPnP and EEP — in small package, drum, tote and bulk quantities with lot control and same-day quotes. Other national distribution options include Univar Solutions and Brenntag North America; Dow and Eastman sell their own branded ranges direct at bulk volumes.
What is the difference between Glycol Ether EB and DB?
EB is ethylene glycol monobutyl ether (CAS 111-76-2), a single-glycol, medium-evaporating solvent. DB is diethylene glycol monobutyl ether (CAS 112-34-5), the two-glycol version, which boils higher and evaporates far more slowly. EB is the cleaning and coatings workhorse; DB is the coalescent you reach for when the film needs to stay open.
Are P-series glycol ethers safer than E-series?
P-series glycol ethers, made from propylene oxide, were developed specifically as lower-toxicity replacements for E-series grades and generally carry less restrictive classifications. “Lower toxicity” is not “non-hazardous” — every grade still requires its own SDS review, and exposure limits differ product by product.
What does the D in DPM, DB and DE stand for?
D indicates the diglycol version — two glycol units in the backbone rather than one. Adding the second glycol unit raises the boiling point and slows evaporation, which is why DB, DE, DM, DPnB and DPnP are all slow-evaporating coalescents while EB and EP are medium to fast.
Is Glycol Ether EB flammable?
No. EB has a flash point of 143 °F, which makes it a Class IIIA combustible liquid rather than a flammable liquid. It ships as UN2369 and does not carry the flammable-liquid storage restrictions that apply to solvents like acetone or hexane.
